Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 5 - Thermochemistry - Exercises - Page 207: 5.63

Answer

$\Delta H = -1300kJ$

Work Step by Step

Using the Hess's law: $P_4 (s) + 3 O_2(g) --> P_4O_6(s) : \Delta H = -1640.1kJ$ $P_4 (s) + 5 O_2(g) --> P_4O_{10}(s) : \Delta H = -2940.1kJ$ 1. Reverse the first equation. $P_4O_6(s) --> P_4 (s) + 3 O_2(g) : \Delta H = +1640.1kJ$ $P_4 (s) + 5 O_2(g) --> P_4O_{10}(s) : \Delta H = -2940.1kJ$ 2. Now, sum the equations: $P_4 (s) + 5 O_2(g) + P_4O_6(s) --> P_4O_{10}(s) + P_4 (s) + 3 O_2(g) : \Delta H = -1300kJ $ *1640.1 - 2940.1 = -1300 $2 O_2(g) + P_4O_6(s) --> P_4O_{10}(s) : \Delta H = -1300kJ$
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