Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 15 - Additional Aqueous Equilibria - Questions for Review and Thought - Topical Questions - Page 693c: 59

Answer

$ K_{sp} (CaF_2) = (6.3 \times 10^{-12})$

Work Step by Step

1. Calculate the molar mass: 40.08* 1 + 19* 2 = 78.08g/mol 2. Calculate the number of moles $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 9.1\times 10^{- 3}}{ 78.08}$ $n(moles) = 1.165\times 10^{- 4}$ Therefore: $C(mol/L) = 1.165\times 10^{- 4}$ 4. Write the $K_{sp}$ expression: $ CaF_2(s) \lt -- \gt 1Ca^{2+}(aq) + 2F^{-}(aq)$ $ K_{sp} = [Ca^{2+}]^ 1[F^{-}]^ 2$ 5. Determine the ions concentrations: $[Ca^{2+}] = [CaF_2] * 1 = [1.165 \times 10^{-4}] * 1 = 1.165 \times 10^{-4}$ $[F^{-}] = [CaF_2] * 2 = 2.331 \times 10^{-4}$ 6. Calculate the $K_{sp}$: $ K_{sp} = (1.165 \times 10^{-4})^ 1 \times (2.331 \times 10^{-4})^ 2$ $ K_{sp} = (1.165 \times 10^{-4}) \times (5.433 \times 10^{-8})$ $ K_{sp} = (6.332 \times 10^{-12})$
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