Answer
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Work Step by Step
Here are the explanations for the Lewis structures, molecular structures, and expected hybrid orbitals for the given sulfur-containing molecules and ions:
a. $SO_{2}$:
- Lewis structure: O=S=O
- Molecular structure: Bent, with a bond angle of approximately 120°
- Hybrid orbitals: sp²
b. $SO_{3}$:
- Lewis structure: O=S=O
- Molecular structure: Trigonal planar
- Hybrid orbitals: sp²
c. $S_{2}O_{3}^{2-}$:
- Lewis structure: O=S-S=O
- Molecular structure: Bent, with a bond angle of approximately 120°
- Hybrid orbitals: sp²
d. $S_{2}O_{8}^{2-}$:
- Lewis structure: O=S-O-O-S=O
- Molecular structure: Bent, with a bond angle of approximately 120°
- Hybrid orbitals: sp²
e. $SO_{3}^{2-}$:
- Lewis structure: O=S=O
- Molecular structure: Trigonal planar
- Hybrid orbitals: sp²
f. $SO_{4}^{2-}$:
- Lewis structure: O=S=O
- Molecular structure: Tetrahedral
- Hybrid orbitals: sp³
g. $SF_{2}$:
- Lewis structure: F-S-F
- Molecular structure: Bent, with a bond angle of approximately 97°
- Hybrid orbitals: sp³
h. $SF_{4}$:
- Lewis structure: F-S-F
- Molecular structure: Seesaw
- Hybrid orbitals: sp³d
i. $SF_{6}$:
- Lewis structure: F-S-F
- Molecular structure: Octahedral
- Hybrid orbitals: sp³d²
j. $F_{3}S-SF$:
- Lewis structure: F-S-F, F-S-F
- Molecular structure: Distorted tetrahedral
- Hybrid orbitals: sp³
k. $SF_{5}^{+}$:
- Lewis structure: F-S-F
- Molecular structure: Trigonal bipyramidal
- Hybrid orbitals: sp³d