Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 22 - Sections 22.1-22.9 - Exercises - Problems by Topic - Page 1069: 30

Answer

See work below for details.

Work Step by Step

The bonds in the boron chloride are stronger and shorter than a typical single bond, which we can explain using valence bond theory and hybridization. The boron atom uses $sp^{2}$ hybridized orbitals to form sigma bonds with the three halogen atoms. Because boron’s three valence electrons are used to form the sigma bonds, the third p orbital of boron is an empty orbital that is perpendicular to the trigonal plane of the molecule. Each halogen atom has a filled p orbital, also perpendicular to the trigonal plane of the molecule. The empty p orbital on the boron atom can overlap with the full p orbitals on the halogens, forming a coordinate-covalent-type second bond. In $BCl_{3}$ , the boron and chlorine are joined by bonds resembling a double bond. Like normal double bonds, the boron–chlorine bond is shorter and stronger than a single bond.
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