Chemistry (7th Edition)

Published by Pearson
ISBN 10: 0321943171
ISBN 13: 978-0-32194-317-0

Chapter 19 - Nuclear Chemistry - Section Problems - Page 836: 53

Answer

Percentage remaining when $t=1000\,y$= 97.2 % Percentage remaining when $t=25000\,y$= 48.7 % Percentage remaining when $t=100000\,y$= 5.61 %

Work Step by Step

Decay constant $\lambda=2.88\times10^{-5}\,y^{-1}$ $t=1000\,y$ Recall that $\ln(\frac{A}{A_{0}})=-\lambda t$ where $A_{0}$ is the amount of sample at the beginning and $A$ is the amount sample after time $t$. $\implies \ln(\frac{A}{A_{0}})=-(2.88\times10^{-5}\,y^{-1})(1000\,y)=-0.0288$ Taking the inverse $\ln$ of both the sides, we have $\frac{A}{A_{0}}=e^{-0.0288}=0.972$ Percentage of the sample remaining=$0.972\times100\%=97.2\%$ When $t=25000\,y$, $ \ln(\frac{A}{A_{0}})=-(2.88\times10^{-5}\,y^{-1})(25000\,y)=-0.0288$ Taking the inverse $\ln$ of both the sides, we have $\frac{A}{A_{0}}=e^{-0.72}=0.487$ Percentage of the sample remaining=$0.487\times100\%=48.7\%$ When $t=100,000\,y$ , $ \ln(\frac{A}{A_{0}})=-(2.88\times10^{-5}\,y^{-1})(100,000\,y)=-2.88$ Taking the inverse $\ln$ of both the sides, we have $\frac{A}{A_{0}}=e^{-2.88}=0.0561$ Percentage of the sample remaining=$0.0561\times100\%=5.61\%$
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