Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 15 - Questions and Problems - Page 712: 15.73

Answer

(a) 1.7 atm$^{-1}$ (b) $P_A$ = 0.69 atm. $P_ B$ = 0.81 atm

Work Step by Step

(a) $$K_p = \frac{P_B}{P_A^2} = \frac{0.60 atm}{0.60^2 atm^2} = 1.7 atm^{-1}$$ (b) $P_A + P_B = 1.5 -> P_B = 1.5 - P_A$ $$1.7= \frac{1.5 - P_A}{P_A^2} $$ $$1.7 P_A^2 + P_A - 1.5 = 0$$ Solving using bhaskara: $$P_{A1} = -1.23 $$ $$P_{A2} = 0.69$$ Pressures cannot be negative, so $P_A$ = 0.69 atm. $P_ B = 1.5 - 0.69 = 0.81 atm$
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