Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 15 - Questions and Problems - Page 709: 15.41

Answer

0.173 mol of $H_2$

Work Step by Step

- Calculate all the concentrations: $$[H_2O] = ( 0.300 )/(10.0) = 0.0300 M$$ $$[CO] = ( 0.300 )/(10.0) = 0.0300 M$$ 1. Write the equilibrium constant expression: - The exponent of each concentration is equal to its balance coefficient. $$K_c = \frac{[Products]}{[Reactants]} = \frac{[ H_2 ][ CO_2 ]}{[ H_2O ][ CO ]}$$ 2. At equilibrium, these are the concentrations of each compound: $[ H_2O ] = 0.0300 \space M - x$ $[ CO ] = 0.0300 \space M - x$ $[ H_2 ] = 0 \space M + x$ $[ CO_2 ] = 0 \space M + x$ $$1.87 = \frac{( x)( x)}{(0.0300 - x)(0.0300 - x)}$$ x = 0.0173 $[H_2] = 0.0173 M$ $n(H_2) = 0.0173 M \times 10.0 L = 0.173 \space mol$
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