Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 8 - Periodic Relationships Among the Elements - Questions & Problems - Page 360: 8.14

Answer

Please see the work below.

Work Step by Step

The first transition series or 3d series consists of 9 elements from Scandium to Copper. Their atomic numbers and electronic configurations can be represented as follows, Scandium, Sc – atomic number – 21. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{1}4s^{2}$ Titanium, Ti – atomic number – 22. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{2}4s^{2}$ Vanadium, V – atomic number – 23. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{3}4s^{2}$ Chromium, Cr – atomic number – 24. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{5}4s^{1}$ Magnesium, Mn – atomic number – 25. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{5}4s^{2}$ Iron, Fe – atomic number – 26. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{6}4s^{2}$ Cobalt, Co – atomic number – 27. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{7}4s^{2}$ Nickel, Ni – atomic number – 28. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{8}4s^{2}$ Copper, Cu – atomic number – 29. Electronic configuration - $1s^{2} 2s^{2}2p^{6} 3s^{2}3p^{6}3d^{10}4s^{1}$ From the electronic configurations, it is clear that the configurations of the inner shell remain the same and there is a difference in the configurations of the valence shell and penultimate shell. Hence the general configurations can be represented as $(n-1)d^{1-10}ns^{1-2}$
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