Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 6 - Thermochemistry - Questions & Problems - Page 262: 6.15

Answer

(a) 0 (b) $-3.1\times10^{2}\,J$ (c) $-1.4\times10^{3}\,J$

Work Step by Step

(a) $w=-P\Delta V=-(0)(5.4\,L-1.6\,L)=0$ Because the external pressure is 0, $w=0$. (b) $w=-P\Delta V=-(0.80\,atm)(5.4\,L-1.6\,L)$ $=-3.04\,L\cdot atm=-3.04\,L\cdot atm\times\frac{101.3\,J}{1\,L\cdot atm}$ $=-3.1\times10^{2}\,J$ (c) $w=-P\Delta V=-(3.7\,atm)(5.4\,L-1.6\,L)$ $=-14.06\,L\cdot atm=-14.06\,L\cdot atm\times\frac{101.3\,J}{1\,L\cdot atm}$ $=-1.4\times10^{3}\,J$
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