Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 3 - Mass Relationships in Chemical Reactions - Questions & Problems - Page 114: 3.135

Answer

Empirical formula = $C_{2}H_{5}Cl$

Work Step by Step

Percentage of Chlorine = 55.0 $6.02\times10^{23} $ H atoms = 1 g Then, $4.19\times10^{23} $ H atoms = $(4.19\times10^{23})\div(6.02\times10^{23})$ = 0.70 g 9.00 g sample contains 0.70 g H Therefore percentage of H in the sample = $(0.70\times100)\div9.00$ = 7.8 Hence percentage of Carbon = 100 –(55.0 + 7.8) = 37.2 Relative no.of atoms =Pecentage/Atomic mass C $37.2\div12$ =3.1 H $7.8\div1$ = 7.8 Cl $55.0\div35.5$ = 1.5 Divide by smallest relative no.of atoms (here 1.5) $3.1\div1.5$ = 2.0 $7.8\div1.5$ = 5.2 $1.5\div1.5$ = 1 Convert to the whole number 2 5 1 Empirical formula = $C_{2}H_{5}Cl$
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