Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 3 - Mass Relationships in Chemical Reactions - Questions & Problems - Page 108: 3.43

Answer

Empirical formula: $$C_6H_{10}S_2O$$ Real molecular formula:$$C_6H_{10}S_2O$$

Work Step by Step

1. Divide all mass percentages by the molar mass of each compound: $$C_{\frac{44.4}{12.01}}H_{\frac{6.21}{1.008}}S_{\frac{39.5}{32.07}}O_{\frac{9.86}{16.00}}$$ $$C_{3.70}H_{6.16}S_{1.23}O_{0.616}$$ 2. Divide all numbers by the smaller one (0.616): $$C_{6.01}H_{10.0}S_{2.00}O_{1}$$ Rounding the number of carbons, we get the empirical formula: $$C_6H_{10}S_2O$$ 3. Calculate the molar mass for the empirical formula: $ C_6H_{10}S_2O $ : ( 1.008 $\times$ 10 )+ ( 12.01 $\times$ 6 )+ ( 16.00 $\times$ 1 )+ ( 32.07 $\times$ 2 )= 162.28 g/mol It is approximately equal to Allicin's molar mass. Therefore, this is the formula for allicin: $$C_6H_{10}S_2O$$
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