Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 22 - Nonmetallic Elements and Their Compounds - Questions & Problems - Page 992: 22.69

Answer

Oxygen forms double bonds in O2, but sulfur forms single bonds in S8 because sulphur can not form stronger double bond . It can form σ– bond as well as π– bond between O and O atoms and exists as O2. Atomic size of sulphur is bigger. It can not form π – bond together with s – bond between S and S atoms. To satisfied its valency it forms S8 molecule in which all atoms of sulphur bonded with only σ– bond .

Work Step by Step

same as above
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