Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 17 - Entropy, Free Energy, and Equilibrium - Questions & Problems - Page 804: 17.17

Answer

(a) $173.4\,kJ/mol$ (b) $8.6\,kJ/mol$ (c) $-2470.4\,kJ/mol$

Work Step by Step

Recall: $\Delta G^{\circ}_{rxn}=\Sigma n\Delta G^{\circ}_{f}(products)-\Sigma m\Delta G_{f}^{\circ}(reactants)$ (a) $\Delta G^{\circ}_{rxn}=[2\Delta G_{f}^{\circ}(NO)]-[\Delta G_{f}^{\circ}(O_{2})+\Delta G_{f}^{\circ}(N_{2})]$ $=[(2)(86.7\,kJ/mol)]-[(0)+(0)]=173.4\,kJ/mol$ (b) $\Delta G^{\circ}_{rxn}=[\Delta G_{f}^{\circ}(H_{2}O(g))]-[\Delta G_{f}^{\circ}(H_{2}O(l))]$ $=(-228.6\,kJ/mol)-(-237.2\,kJ/mol)=8.6\,kJ/mol$ (c) $\Delta G^{\circ}_{rxn}=[4\Delta G_{f}^{\circ}(CO_{2})+2\Delta G_{f}^{\circ}(H_{2}O(l))]-[2\Delta G_{f}^{\circ}(C_{2}H_{2})+5\Delta G_{f}^{\circ}(O_{2})]$ $=[(4)(-394.4\,kJ/mol)+(2)(-237.2\,kJ/mol)]-[(2)(209.2\,kJ/mol)+(5)(0\,kJ/mol)]$ $=-2470.4\,kJ/mol$
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