Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 11 - Intermolecular Forces and Liquids and Solids - Questions & Problems - Page 514: 11.119

Answer

The distance between $Li^{+}$ and $Cl^{-}$ is longer in solid phase than gas phase because in solid phase, all the ions are close to each other. So each $Li^{+}$ ion attracts many $Cl^{-}$ ions and thus the distance between ions increases. Whereas in gas phase, ions are very far from each other, so $Li^{+}$ is more attracted to the $Cl^{-}$ ion it is bonded to and thus the distance is less. The $Li^{+}$ and $Cl^{-}$ ions are much closer to each other in gas phase.

Work Step by Step

The distance between $Li^{+}$ and $Cl^{-}$ is longer in solid phase than gas phase because in solid phase, all the ions are close to each other. So each $Li^{+}$ ion attracts many $Cl^{-}$ ions and thus the distance between ions increases. Whereas in gas phase, ions are very far from each other, so $Li^{+}$ is more attracted to the $Cl^{-}$ ion it is bonded to and thus the distance is less. The $Li^{+}$ and $Cl^{-}$ ions are much closer to each other in gas phase.
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