Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 2 - Chemical Formulas and Composition Stoichiometrhy - Exercises - Composition Stoichiometry - Page 76: 52

Answer

Simplest formula of timolol is $C_{13}H_{24}N_{4}O_{3}S$ Molecular formula of timolol is $C_{13}H_{24}N_{4}O_{3}S$

Work Step by Step

First, we need to calculate the mass of each element in 3.16g timolol using the percent composition: Mass of C=$total mass\times percent mass=3.16\times\frac{49.4}{100}=1.56104g$ Mass of H=$total mass\times percent mass=3.16\times\frac{7.64}{100}=0.241424g$ Mass of N=$total mass\times percent mass=3.16\times\frac{17.7}{100}=0.55932g$ Mass of O=$total mass\times percent mass=3.16\times\frac{15.2}{100}=0.48032g$ Mass of S=$total mass\times percent mass=3.16\times\frac{10.1}{100}=0.31916g$ Then we calculate the number of moles of each element using the formula: Number of moles=$\frac{mass}{moleculat mass}$ Number of moles of C=$\frac{1.56104}{12}\approx0.13 amu$ Number of moles of H=$\frac{0.241424}{1}\approx0.24 amu$ Number of moles of N=$\frac{0.55932}{14}\approx0.04 amu$ Number of moles of O=$\frac{0.48032}{12}\approx0.03 amu$ Number of moles of S=$\frac{0.31916}{32}\approx0.01 amu$ Finally, we calculate the ratio of elements to the lowest number of mole element. The ratio of C to S$=\frac{0.13}{0.01}=13$ The ratio of H to S$=\frac{0.24}{0.01}=24$ The ratio of N to S$=\frac{0.04}{0.01}=4$ The ratio of O to S$=\frac{0.03}{0.01}=3$ The simplest formula is $C_{13}H_{24}N_{4}O_{3}S$ The molar mass of timolol can be calculated using the formula: Molar mass$=\frac{mass}{number of moles}=\frac{3.16}{0.001}=316 amu$ The simplest formula of timolol molar mass$=13\times12+24\times1+4\times14+3\times16+1\times32=316amu$ Since the simplest formula of timolol molar mass is similar to timolol molar mass So, the simplest formula of timolol is the molecular formula of timolol $C_{13}H_{24}N_{4}O_{3}S$.
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