Answer
$W$ is not a vector subspace of $M_{3,1}$.
Work Step by Step
Let $u=\left[\begin{array}{lll}{2} & {0} & {\sqrt{2}}\end{array}\right]^{T}\in W$ and $c=2\in R$. Now,
$$cu=2\left[\begin{array}{lll}{2} & {0} & {\sqrt{2}}\end{array}\right]^{T}=\left[\begin{array}{lll}{2} & {0} & {2\sqrt{2}}\end{array}\right]^{T}$$
which is not an element of $W$. Hence, $W$ is not a vector subspace of $M_{3,1}$.