Answer
See below.
Work Step by Step
Let $x$ be the amount of Earl Grey Tea, then $100-x$ is the amount of Orange Pekoe Tea.
Then our equation is: $5x+3(100-x)=100\cdot4.5\\5x+300-3x=450\\2x=150\\x=75$
Thus we have to mix 75 lbs. of Early Grey Tea with 25 lbs. of Orange Pekoe Tea.