Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 16 - A Macroscopic Description of Matter - Exercises and Problems - Page 466: 58

Answer

a) $301\;\rm K$ b) $338\;\rm K$

Work Step by Step

a) First of all, we need to find the temperature of the gas at point 1 before it goes under the isothermal process or the other process. We know, for an ideal gas, that $$P_1V_1=nRT_1$$ Hence, $$T_1=\dfrac{P_1V_1}{nR}$$ Plugging the known from the given graph; $$T_1=\dfrac{(100\times 10^3)(2)}{(80)(8.31)}$$ $$T_1=\color{red}{\bf 301}\;\rm K$$ which is the temperature of the isothermal process. --- b) We can use the straight line equation of $y=mx+b$ where $y$ here is $P$ and $x$ here is $V$. Also, $m$ is the slope of the line, and $b$ is a constant we can find by plugging the data at point 1. $$P=mV+b$$ The slope of the line is given by $\dfrac{P_2-P_1}{V_1-V_2}$. $$P=\dfrac{P_2-P_1}{V_1-V_2}V+b$$ $$P=\dfrac{200,000-100,000}{1-2}V+b$$ $$P=-10^5V+b$$ Use point 1 data; $$P_1=-10^5V_1+b$$ $$100,000=-10^5(2)+b$$ Hence, $$b=3\times 10^5$$ Thus, $$P=-10^5V+(3\times10^{5})$$ Therefore, $$P=( 3-V)\times 10^5\tag 1$$ Using the ideal gas law $$PV=nRT$$ So, $$( 3-V)V\times 10^5=nRT$$ Hence, $$T=\dfrac{(3V-V^2)\times 10^5}{nR}$$ Now we need to maximize $T$, so we will take the derivative of $dT/dV=0$; $$\dfrac{dT}{dV}=0=\dfrac{(3-2V_{max})\times 10^5}{nR}$$ Hence, $$V_{max}=1.5\;\rm m^3$$ which is the distance between the two volumes, the initial and the final. Hence, the temperature there is given by $$T_{max}=\dfrac{PV_{max}}{nR}=\dfrac{(150\times 10^3)(1.5)}{(80)(8.31)}$$ $$T_{\rm max}=\color{red}{\bf 338}\;\rm K$$
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