General Chemistry 10th Edition

Published by Cengage Learning
ISBN 10: 1-28505-137-8
ISBN 13: 978-1-28505-137-6

Chapter 3 - Calculations with Chemical Formulas and Equations - Questions and Problems - Page 120: 3.57

Answer

a - Mass percentage of C = 42.9 % Mass percentage of O = 57.1 % b- Mass percentage of C = 60.0 % Mass percentage of O = 40 % c- Mass percentage of Na = 19.2 % Mass percentage of H= 1.67 % Mass percentage of P= 25.8 % Mass percentage of O = 53.3 % d- Mass percentage of Co= 32.2 % Mass percentage of N= 15.3 % Mass percentage of O = 52.5 %

Work Step by Step

Strategy: To calculate the mass percentage of elements in the compound : 1- calculate the Molar mass of the compound 2- Calculate the mass of each element to the Molar mass and express this in percentage. a - To find the mass percentage of C and O in CO, first find the Molar mass of CO. Molar mass of CO = 1 x 12.0 + 1 x 16.0 Molar mass of CO = 28 g/mol ( to three significant figures) Based on the chemical formula CO, in 1 mole of CO , there is 1 mole of C, 1 mole of O. Mass percentage of C = $\frac{mass_(1 C mole)}{Molar mass_(CO)}$$\times$ 100% Mass percentage of C = $\frac{12.0}{28.0}$$\times$ 100% Mass percentage of C = 42.9 % Mass percentage of O = $\frac{mass_(1 O mole)}{Molar mass_(CO)}$$\times$ 100% Mass percentage of O = $\frac{16.0}{28.0}$$\times$ 100% Mass percentage of O = 57.1 % b - $CO_{2}$. Molar mass of $CO_{2}$. Molar mass of $CO_{2}$ = 2 x 12.0 + 1 x 16.0 Molar mass of $CO_{2}$ = 40.0 g/mol ( to three significant figures) Based on the chemical formula $CO_{2}$, in 1 mole of $CO_{2}$, there re 2 mole of C, 1 mole of O. Mass percentage of C = $\frac{mass_(2 C mole)}{Molar mass_(CO_{2})}$$\times$ 100% Mass percentage of C = $\frac{2x12.0}{40.0}$$\times$ 100% Mass percentage of C = 60.0 % Mass percentage of O = $\frac{mass_(1 O mole)}{Molar mass_(CO_{2})}$$\times$ 100% Mass percentage of O = $\frac{16.0}{40.0}$$\times$ 100% Mass percentage of O = 40 % c - $NaH_{2}PO_{4}$ Molar mass of $NaH_{2}PO_{4}$ = 1 x 23.0 + 2 x 1.00 +1 x 31.0 4x 16.0 Molar mass of $NaH_{2}PO_{4}$ = 120 g/mol ( to three significant figures) Based on the chemical formula$NaH_{2}PO_{4}$, in 1 mole of $NaH_{2}PO_{4}$, there are 1 mole Na, 2 mole H, 1 mole of P and 4 mole O. Mass percentage of Na = $\frac{mass_(1 Na mole)}{Molar mass_(NaH_{2}PO_{4})}$$\times$ 100% Mass percentage of Na = $\frac{2 X 23.0}{120}$$\times$ 100% Mass percentage of Na = 19.2 % Mass percentage of H = $\frac{mass_(2 H mole)}{Molar mass_(NaH_{2}PO_{4})}$$\times$ 100% Mass percentage of H = $\frac{2 X 1.00}{120}$$\times$ 100% Mass percentage of H= 1.67 % Mass percentage of P = $\frac{mass_(1 mole mole)}{Molar mass_(NaH_{2}PO_{4})}$$\times$ 100% Mass percentage of P= $\frac{31.0}{120}$$\times$ 100% Mass percentage of P= 25.8 % Mass percentage of O = $\frac{mass_(4 O mole)}{Molar mass_(NaH_{2}PO_{4})}$$\times$ 100% Mass percentage of O = $\frac{4X 16.0}{120.0}$$\times$ 100% Mass percentage of O = 53.3 % d - $Co(NO_{3})_2$ Molar mass of $Co(NO_{3})_2$ = 1 x 59.0 +2 x 14.0+ 6 x 16.0 Molar mass of $Co(NO_{3})_2$ = 183 g/mol ( to three significant figures) Based on the chemical formula in 1 mole of $Co(NO_{3})_2$, there are 1 mole Co, 2 mole N and 6 mole O. Mass percentage of Co= $\frac{mass_(1 Co mole)}{Molar mass_(Co(NO_{3})_2)}$$\times$ 100% Mass percentage of Co= $\frac{59.0}{183}$$\times$ 100% Mass percentage of Co= 32.2 % Mass percentage of N= $\frac{mass_(2 N mole)}{Molar mass_(NaH_{2}PO_{4})}$$\times$ 100% Mass percentage of N= $\frac{2X14.0}{183}$$\times$ 100% Mass percentage of N= 15.3 % Mass percentage of O = $\frac{mass_(6 O mole)}{Molar mass_(NaH_{2}PO_{4})}$$\times$ 100% Mass percentage of O = $\frac{6X 16.0}{183}$$\times$ 100% Mass percentage of O = 52.5 %
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