- Carathis
- Vathek's mother. She is a Greek woman who is well versed in science, astrology, and occult magic. She teaches all of her skills to Vathek, and convinces him to embark on his quest for power which eventually leads to his damnation. When arriving in hell, Carathis runs amok, exploring the palace, discovering its hidden secrets, and even tries to stage a rebellion. However, once her own punishment is enacted, she too loses all hope and is consumed by her guilt.
- Vathek
- Ninth Caliph of the Abassides, who ascended to the throne at an early age. His figure was pleasing and majestic, but when angry, his eyes became so terrible that "the wretch on whom it was fixed instantly fell backwards and sometimes expired" (1). He was addicted to women and pleasures of the flesh, so he ordered five palaces to be built: the five palaces of the senses. Although he was an eccentric man, he was learned in the ways of science, physics, and astrology. His chief sin, gluttony, paved the path of his damnation.
- Giaour
- His name means blasphemer and infidel. He claims to be an Indian merchant, but in actuality he is a Jinn who works for the arch-demon Eblis. He guides Vathek and gives him instructions on how to reach the palace of fire.
- Emir Fakreddin
- Vathek's host during his travels. He offers Vathek a place to stay and rest. He is deeply religious. Vathek betrays his hospitality by seducing his daughter.
- Nouronihar
- The Emir's daughter, a beautiful girl who is promised to Gulchenrouz, but is seduced by Vathek and joins him in his road to damnation.
- Gulchenrouz
- A beautiful young man with feminine features. He is the Emir's nephew. Due to his innocence, he is rescued from Carathis's hands and is allowed to live in eternal youth in a palace above the clouds.
- Bababalouk
- Head of Vathek's eunuchs. He is cunning and acts as a steward on Vathek's journey.
- Morakanabad
- Vathek's loyal and unsuspecting vizier.
- Sutlememe
- The Emir's head eunuch who serves as a caretaker for Nouronihar and Gulchenrouz.
- Dilara
- Vathek's favourite wife.
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