- Lucy is the youngest of four siblings. In some respects, she is the primary character of the story. She is the first to discover the land of Narnia, which she enters inadvertently when she steps into a wardrobe while exploring the Professor's house. When Lucy tells her three siblings about Narnia, they do not believe her: Peter and Susan think she is just playing a game, while Edmund persistently ridicules her. In Narnia, she is crowned Queen Lucy the Valiant.
- Edmund is the second-youngest of four siblings. He has a bad relationship with his brother and sisters. Edmund is known to be a liar, and often harasses Lucy. Lured by the White Witch's promise of power and an unlimited supply of magical treats, Edmund betrays his siblings. He later repents and helps defeat the White Witch. He is eventually crowned King Edmund the Just.
- Susan is the second-oldest sibling. She does not believe in Narnia until she actually goes there. She and Lucy accompany Aslan on the journey to the Stone Table, where he allows the Witch to take his life in place of Edmund's. Tending to Aslan's carcass, she removes a muzzle from him to restore his dignity and oversees a horde of mice who gnaw away his bonds. She then shares the joy of his resurrection and the endeavor to bring reinforcements to a critical battle. Susan is crowned Queen Susan the Gentle.
- Peter is the eldest sibling. He judiciously settles disputes between his younger brother and sisters, often rebuking Edmund for his attitude. Peter also disbelieves Lucy's stories about Narnia until he sees it for himself. He is hailed as a hero for the slaying of Maugrim and for his command in the battle to overthrow the White Witch. He is crowned High King of Narnia and dubbed King Peter the Magnificent.
- Aslan, a lion, is the rightful King of Narnia and other magic countries. He sacrifices himself to save Edmund, but is resurrected in time to aid the denizens of Narnia and the Pevensie children against the White Witch and her minions. As the "son of the Emperor-Over-the-Sea" (an allusion to God the Father), Aslan is the all-powerful creator of Narnia. Lewis revealed that he wrote Aslan as a portrait, although not an allegorical portrait, of Christ.[8]
- The White Witch is the land's self-proclaimed queen and the primary antagonist of the story. Her reign in Narnia has made winter persist for a hundred years with no end in sight. When provoked, she turns creatures to stone with her wand. She fears the fulfilment of a prophecy that "two sons of Adam and two daughters of Eve" (meaning two male humans and two female humans) will supplant her. She is usually referred to as "the White Witch", or just "the Witch". Her actual name, Jadis, appears once in the notice left on Tumnus's door after his arrest. Lewis later wrote a prequel to include her back story and account for her presence in the Narnian world.
- The Professor is a kindly old gentleman who takes the children in when they are evacuated from London. He is the first to believe that Lucy did indeed visit a land called Narnia. He tries to convince the others logically that she did not make it up. After the children return from Narnia, he assures them that they will return one day. The book hints that he knows more of Narnia than he lets on (hints expanded upon in later books of the series).
- Tumnus, a faun, is the first individual Lucy (who calls him "Mr. Tumnus") meets in Narnia. Tumnus befriends Lucy, despite the White Witch's standing order to turn in any human he finds. He initially plans to obey the order but, after getting to like Lucy, he cannot bear to alert the Witch's forces. He instead escorts her back towards the safety of her own country. His good deed is later given away to the Witch by Edmund. The witch orders Tumnus arrested and turns him to stone, but he is later restored to life by Aslan.
- Mr. and Mrs. Beaver, two beavers, are friends of Tumnus. They play host to Peter, Susan and Lucy and lead them to Aslan.
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