University Physics with Modern Physics (14th Edition)

Published by Pearson
ISBN 10: 0321973615
ISBN 13: 978-0-32197-361-0

Chapter 41 - Quantum Mechanics II: Atomic Structure - Problems - Exercises - Page 1404: 41.52

Answer

See explanation.

Work Step by Step

For large values of n, the inner electrons almost completely shield the nucleus. The effective atomic number is 1, and the ionization energy is $\frac{13.6eV}{n^2}$. b. The ionization energy is $\frac{13.6eV}{300^2}=1.51\times10^{-4}eV$. In the Bohr model, $r_n=n^2a$. Calculate the orbital radius. $$r_{300}=300^2(0.529\times10^{-10}m)=4.76\times10^{-6}m$$ c. Repeat the calculation. The ionization energy is $\frac{13.6eV}{600^2}=3.78\times10^{-5}eV$. Calculate the orbital radius. $$r_{600}=600^2(0.529\times10^{-10}m)=1.90\times10^{-5}m$$
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