University Physics with Modern Physics (14th Edition)

Published by Pearson
ISBN 10: 0321973615
ISBN 13: 978-0-32197-361-0

Chapter 41 - Quantum Mechanics II: Atomic Structure - Problems - Exercises - Page 1404: 41.50

Answer

P(r) has its maximum value at the Bohr radius, a.

Work Step by Step

At the r where P(r) has its maximum value, $\frac{d}{dr}r^2|\Psi|^2=0$. Using a result from Example 41.4, $r^2|\Psi|^2=Cr^2e^{-2r/a}$ Find the derivative. $\frac{d}{dr}r^2|\Psi|^2= Ce^{-2r/a}(2r-\frac{2r^2}{a})$ This derivative is zero for r=a. P(r) has its maximum value at the distance of the electron from the nucleus in the Bohr model. This agrees with Figure 41.8 in the textbook.
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