Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 40 - One-Dimensional Quantum Mechanics - Exercises and Problems - Page 1214: 41

Answer

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Work Step by Step

We are dealing with an electron in a finite potential well. $$\color{blue}{\bf [a]}$$ The wave function $ \psi(x) $ for the electron in the classically forbidden region at $ x = L $ is given by $$ \psi(x) = \psi_{\text{edge}} \;e^{-(x - L)/\eta}\tag 1 $$ The ratio of the probability densities at two positions, $ x = L $ and $ x = L + d $, is: $$ \frac{P(d + L)}{P(L)} = \frac{|\psi(d + L)|^2}{|\psi(L)|^2}=10\%=0.10 $$ Substitute from (1); $$ \frac{P(d + L)}{P(L)} = \frac{|\psi_{\text{edge}} \; e^{-d/\eta}|^2}{|\psi_{\text{edge}}|^2\;e^0} = e^{-2d/\eta}=0.10 $$ $$ e^{-2d/\eta}=0.10\tag 2$$ Now we need to find $\eta$ which is given by $$ \eta = \frac{\hbar}{\sqrt{2m(U_0 - E)}} $$ where $ U_0 - E = 2.7 \; \text{eV} $ The electron in sodium metal has an energy of $\rm -2.7 eV$, which means it is trapped inside the metal. The energy difference, $ U_0 - E = 2.7 \, \text{eV} $, where $ U_0 $ is the surface's potential energy barrier, shows how much energy is keeping the electron inside. So the electron's penetration depth is $$ \eta = \frac{(1.05 \times 10^{-34})}{\sqrt{2 (9.11 \times 10^{-31}) (2.7\times 1.6\times 10^{-19})}}=\bf 1.18 \times 10^{-10} \;\rm m $$ $$ \eta =\bf \; 0.118 \; \rm \text{nm}\tag 3 $$ Solving (2) for $ d $ by taking the natural logarithm of both sides; $$ \dfrac{-2d}{\eta }= \ln(0.10) $$ $$d=\dfrac{ \eta\;\ln(0.10)}{-2}$$ Substitute from (3); $$d=\dfrac{ (0.118 )\;\ln(0.10)}{-2}=\color{red}{\bf 0.136}\;\rm nm$$ $$\color{blue}{\bf [b]}$$ A typical atomic diameter is approximately $ 2a_B $, where $ a_B $ is the Bohr radius, which is about $ 0.1 \; \text{nm} $. The penetration distance of $ 0.118 \; \text{nm} $ is on the same order of magnitude as the atomic diameter. Thus, the penetration distance of the electron beyond the surface is roughly one atomic diameter.
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