Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 40 - One-Dimensional Quantum Mechanics - Exercises and Problems - Page 1212: 2

Answer

${\bf 1.5}\;\rm nm$

Work Step by Step

$$\color{blue}{\bf [a]}$$ We know that the range of wavelength regions is given by: Infrared (IR): $700 \; \rm{nm}$ to $1 \; \rm{mm}$ Visible light: $400 \;\rm{nm}$ to $700 \;\rm{nm}$ Ultraviolet (UV):$10 \; \rm{nm}$ to $400 \; \rm{nm}$ X-rays :$0.01 \; \rm{nm}$ to $ 10 \; \rm{nm}$ So the 1484-nm-photon is in the $\color{red}{\bf infrared}$ range. $$\color{blue}{\bf [b]}$$ We know, for a particle in a one-dimensional box, that the energy levels are given by $$ E_n = \frac{n^2 h^2}{8mL^2}\tag 1 $$ And we know that the energy difference between the $ n = 3 $ and So, $$ E_{\rm photon}=\Delta E$$ $$\frac{hc}{\lambda} = E_3 - E_2$$ Using (1); $$\frac{hc}{\lambda} = \frac{9h^2}{8mL^2} - \frac{4h^2}{8mL^2} = \frac{5h^2}{8mL^2} $$ Thus, $$ \frac{ c}{\lambda}=\frac{5h}{8mL^2} $$ Solving for $L$ to find the length of the box in which the electrons are confined. $$ L =\sqrt{ \frac{5h\lambda}{8mc}}$$ Substituting the known; $$ L =\sqrt{ \frac{5 (6.63 \times 10^{-34}) (1484 \times 10^{-9})}{8 (9.11 \times 10^{-31}) (3 \times 10^8)}}$$ $$L=\color{red}{\bf 1.5}\;\rm nm$$
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