General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 7 - Chemical Reactions and Quantities - 7.9 Energy in Chemical Reactions - Questions and Problems - Page 274: 7.94

Answer

a. 850 kJ. b. 278 kJ.

Work Step by Step

a. - Find the conversion factors: $ CH_3OH $ : ( 1.008 $\times$ 4 )+ ( 12.01 $\times$ 1 )+ ( 16.00 $\times$ 1 )= 32.04 g/mol $$ \frac{1 \space mole \space CH_3OH }{ 32.04 \space g \space CH_3OH } \space and \space \frac{ 32.04 \space g \space CH_3OH }{1 \space mole \space CH_3OH }$$ According to the balanced equation: $$ \frac{ 2 \space moles \space CH_3OH }{ -726 \space kJ} \space and \space \frac{ -726 \space kJ}{ 2 \space moles \space CH_3OH }$$ - Find the total energy using these conversion factors: $$ 75.0 \space g \space CH_3OH \times \frac{1 \space mole \space CH_3OH }{ 32.04 \space g \space CH_3OH } \times \frac{ -726 \space kJ}{ 2 \space moles \space CH_3OH } = -850. \space kJ$$ b. - Find the conversion factors: $ Ca(OH)_2 $ : ( 40.08 $\times$ 1 )+ ( 1.008 $\times$ 2 )+ ( 16.00 $\times$ 2 )= 74.10 g/mol $$ \frac{1 \space mole \space Ca(OH)_2 }{ 74.10 \space g \space Ca(OH)_2 } \space and \space \frac{ 74.10 \space g \space Ca(OH)_2 }{1 \space mole \space Ca(OH)_2 }$$ According to the balanced equation: $$ \frac{ 1 \space mole \space Ca(OH)_2 }{ 65.3 \space kJ} \space and \space \frac{ 65.3 \space kJ}{ 1 \space mole \space Ca(OH)_2 }$$ - Find the total energy using these conversion factors: $$ 315 \space g \space Ca(OH)_2 \times \frac{1 \space mole \space Ca(OH)_2 }{ 74.10 \space g \space Ca(OH)_2 } \times \frac{ 65.3 \space kJ}{ 1 \space mole \space Ca(OH)_2 } = 278 \space kJ$$
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