General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 7 - Chemical Reactions and Quantities - 7.9 Energy in Chemical Reactions - Questions and Problems - Page 274: 7.96

Answer

a. Exothermic. b. 35.5 kcal c. 176 g of $C_2H_6O$

Work Step by Step

a. Since the energy is in the products, this is an exothermic reaction. b. - Find the conversion factors: $ C_2H_6O $ : ( 1.008 $\times$ 6 )+ ( 12.01 $\times$ 2 )+ ( 16.00 $\times$ 1 )= 46.07 g/mol $$ \frac{1 \space mole \space C_2H_6O }{ 46.07 \space g \space C_2H_6O } \space and \space \frac{ 46.07 \space g \space C_2H_6O }{1 \space mole \space C_2H_6O }$$ According to the balanced equation: $$ \frac{ 1 \space mole \space C_2H_6O }{ 327 \space kcal} \space and \space \frac{ 327 \space kcal}{ 1 \space mole \space C_2H_6O }$$ - Find the total energy using these conversion factors: $$ 5.00 \space g \space C_2H_6O \times \frac{1 \space mole \space C_2H_6O }{ 46.07 \space g \space C_2H_6O } \times \frac{ 327 \space kcal}{ 1 \space mole \space C_2H_6O } = 35.5 \space kcal$$ c.- Find the conversion factors: $ C_2H_6O $ : ( 1.008 $\times$ 6 )+ ( 12.01 $\times$ 2 )+ ( 16.00 $\times$ 1 )= 46.07 g/mol $$ \frac{1 \space mole \space C_2H_6O }{ 46.07 \space g \space C_2H_6O } \space and \space \frac{ 46.07 \space g \space C_2H_6O }{1 \space mole \space C_2H_6O }$$ According to the balanced equation: $$ \frac{ 1 \space mole \space C_2H_6O }{ 327 \space kcal} \space and \space \frac{ 327 \space kcal}{ 1 \space mole \space C_2H_6O }$$ And finally, since the energy is in kJ: $$\frac{4.184 \space kJ}{1 \space kcal} and \frac{1 \space kcal}{4.184 \space kJ}$$ - Find the total energy using these conversion factors: $$ 1250 \space kJ \times \frac{1 \space kcal}{4.184 \space kJ} \times \frac{ 1 \space mole \space C_2H_6O }{ 327 \space kcal} \times \frac{ 46.07 \space g \space C_2H_6O }{1 \space moles \space C_2H_6O } = 176 \space g \space C_2H_6O$$
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