General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 11 - Acids and Bases - 11.6 The pH Scale - Questions and Problems - Page 422: 11.49

Answer

a. pH = 4.0 b. pH = 8.5 c. pH = 9.0 d. pH = 3.40 e. pH = 7.17 f. pH = 10.92

Work Step by Step

a.$$pH = -log[H_3O^+] = -log( 1 \times 10^{-4} ) = 4.0 $$ b. $$pH = -log[H_3O^+] = -log( 3 \times 10^{-9} ) = 8.5 $$ c. $$[H_3O^+] = \frac{1.0 \times 10^{-14}}{[OH^-]} = \frac{1.0 \times 10^{-14}}{ 1 \times 10^{-5} } = 1. \times 10^{-9} \space M$$ $$pH = -log[H_3O^+] = -log( 1. \times 10^{-9} ) = 9.0 $$ d. $$[H_3O^+] = \frac{1.0 \times 10^{-14}}{[OH^-]} = \frac{1.0 \times 10^{-14}}{ 2.5 \times 10^{-11} } = 4.0 \times 10^{-4} \space M$$ $$pH = -log[H_3O^+] = -log( 4.0 \times 10^{-4} ) = 3.40 $$ e.$$pH = -log[H_3O^+] = -log( 6.7 \times 10^{-8} ) = 7.17 $$ $$[H_3O^+] = \frac{1.0 \times 10^{-14}}{[OH^-]} = \frac{1.0 \times 10^{-14}}{ 8.2 \times 10^{-4} } = 1.2 \times 10^{-11} \space M$$ f.$$pH = -log[H_3O^+] = -log( 1.2 \times 10^{-11} ) = 10.92 $$
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