General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 11 - Acids and Bases - 11.6 The pH Scale - Questions and Problems - Page 422: 11.50

Answer

a. 8.0 b. 5.3 c. 12.0 d. 11.92 e. 1.33 f. 8.59

Work Step by Step

a. $$pH = -log[H_3O^+] = -log( 1 \times 10^{-8} ) = 8.0 $$ b. $$pH = -log[H_3O^+] = -log( 5 \times 10^{-6} ) = 5.3 $$ c. $$[H_3O^+] = \frac{1.0 \times 10^{-14}}{[OH^-]} = \frac{1.0 \times 10^{-14}}{ 0.01 } = 1. \times 10^{-12} \space M$$ $$pH = -log[H_3O^+] = -log( 1. \times 10^{-12} ) = 12.0 $$ d. $$[H_3O^+] = \frac{1.0 \times 10^{-14}}{[OH^-]} = \frac{1.0 \times 10^{-14}}{ 8.0 \times 10^{-3} } = 1.2 \times 10^{-12} \space M$$ $$pH = -log[H_3O^+] = -log( 1.2 \times 10^{-12} ) = 11.92 $$ e. $$pH = -log[H_3O^+] = -log( 4.7 \times 10^{-2} ) = 1.33 $$ f. $$[H_3O^+] = \frac{1.0 \times 10^{-14}}{[OH^-]} = \frac{1.0 \times 10^{-14}}{ 3.9 \times 10^{-6} } = 2.6 \times 10^{-9} \space M$$ $$pH = -log[H_3O^+] = -log( 2.6 \times 10^{-9} ) = 8.59 $$
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