General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 11 - Acids and Bases - 11.4 Dissociation Constants for Acids and Bases - Questions and Problems - Page 413: 11.32

Answer

$$C_6H_5-NH_2(aq) + H_2O(l) \leftrightharpoons C_6H_5-NH{_3}^+(aq) + OH^-(aq)$$ $$K_b = \frac{[OH^-][ C_6H_5-NH{_3}^+]}{[ C_6H_5-NH_2]} = 4.0 \times 10^{-10}$$

Work Step by Step

1. Write the reactants and products: Aniline: $C_6H_5-NH_2$ Water: $H_2O$ Conjugate acid: $C_6H_5-NH{_3}^+$ Hydroxide ion: $OH^-$ 2. Write the equation: $$C_6H_5-NH_2(aq) + H_2O(l) \leftrightharpoons C_6H_5-NH{_3}^+(aq) + OH^-(aq)$$ 3. The $K_b$ expression follows this pattern: $$K_b = \frac{[OH^-][Conj. \space Acid]}{[Base]}$$ Substituting the compounds: $$K_b = \frac{[OH^-][ C_6H_5-NH{_3}^+]}{[ C_6H_5-NH_2]} = 4.0 \times 10^{-10}$$
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