General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 11 - Acids and Bases - 11.4 Dissociation Constants for Acids and Bases - Questions and Problems - Page 413: 11.29

Answer

a. $H_2SO_3$ is the stronger acid. b. $HS{O_3}^-$ is the conjugate base of $H_2SO_3$ c. $H_2SO_3$ has the weaker conjugate base. d. $HS^-$ has the stronger conjugate base. e. $H_2SO_3$ produces more ions.

Work Step by Step

a. Since $H_2SO_3$ has a larger $K_a$ value than $HS^-$, it is a stronger acid. $$1.2 \times 10^{-2} \gt 1.3 \times 10^{-19}$$ b. As we can see by the reaction, when $H_2SO_3$ loses a proton, it produces $HS{O_3}^-$. c. The stronger the acid, the weaker its conjugate base. Therefore, $H_2SO_3$ has the weaker conjugate base. d. The weaker the acid, the stronger its conjugate base. Thus, $HS^-$ has the stronger conjugate base. e. The stronger acid produces more ions. So, $H_2SO_3$ produces more ions.
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