Answer
$100^{\circ}$Steam would be more scalding if it came in contact with your skin.
Steam has latent heat whether hot water has internal energy only.
Work Step by Step
$100^{\circ}$Steam would be more scalding if it came in contact with your skin because steam has latent heat as well as internal energy but hot water has only internal energy.
Steam has latent heat whether hot water has internal energy only is the difference between them.
