Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 7 - Periodic Properties of the Elements - Exercises - Page 293: 7.46a

Answer

The electron configuration for $Ru^{3+}$ is $$Ru^{3+}: [Kr]4d^5$$ $Ru^{3+}$ does not have noble-gas configuration.

Work Step by Step

*RULES TO WRITE ELECTRON CONFIGURATIONS FOR IONS: - When electrons are removed to form cations, those of the orbitals that have the largest principal quantum number $n$ will be removed first. - If there are more than one subshell for a given $n$, electrons of the subshell with the highest value of $l$ will be removed first. - When electrons are added to form anions, they would be added to the empty or partially occupied orbital with the lowest value of $n$. 1) The electron configuration of a neutral $Ru$ atom is $$Ru: [Kr]4d^{7}5s^1$$ 2) Here we need to find the electron configuration for $Ru^{3+}$, an ion having 3 electrons removed from a neutral $Ru$ atom. Therefore, according to the rules, when electrons are removed, we would look for the orbital with the largest $n$ first. Here, subshell $5s$, with $n=5$, have the largest $n$. There are 1 electron occupying subshell $5s$ in a neutral $Ru$ atom. That electron would be removed first. However, still 2 more are needed to remove so that $Ru^{3+}$ can be made. 3) The subshells with the next largest value of $n$ is $4s$, $4p$ and $4d$. Among those, subshell $4d$ has the largest $l$ $(l=2)$. So electrons in subshell $4d$ would be considered first. Subshell $4d$ is occupied by 7 electrons in neutral $Ru$ atom. 2 electrons among these would be removed so that eventually 3 electrons would be removed to create $Ru^{3+}$. That means the electron configuration for $Ru^{3+}$ is $$Ru^{3+}: [Kr]4d^5$$ The above configuration is not the configuration of any noble gases, so $Ru^{3+}$ does not have noble-gas configuration.
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