Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 7 - Periodic Properties of the Elements - Exercises - Page 293: 7.45b

Answer

The electron configuration for $Sn^{2+}$ is $$Sn^{2+}: [Kr]4d^{10}5s^2$$ $Sn^{2+}$ does not have noble-gas configuration.

Work Step by Step

*RULES TO WRITE ELECTRON CONFIGURATIONS FOR IONS: - When electrons are removed to form cations, those of the orbitals that have the largest principal quantum number $n$ will be removed first. - If there are more than one subshell for a given $n$, electrons of the subshell with the highest value of $l$ will be removed first. - When electrons are added to form anions, they would be added to the empty or partially occupied orbital with the lowest value of $n$. 1) The electron configuration of a neutral $Sn$ atom is $$Sn: [Kr]4d^{10}5s^25p^2$$ 2) Here we need to find the electron configuration for $Sn^{2+}$, an ion having 2 electrons removed from a neutral $Sn$ atom. Therefore, according to the rules, when electrons are removed, we would look for the orbital with the largest $n$. Here, both subshell $5s$ and subshell $5p$, with $n=5$, have the largest $n$. 3) So we move to the next rule: look for the subshell with the highest value of $l$ first. Subshell $5p$ $(l=1)$ has a higher value of $l$ than subshell $5s$ $(l=0)$. So we would consider subshell $5p$ first. There are 2 electrons occupying subshell $5p$ in a neutral $Sn$ atom. Therefore, to make $Sn^{2+}$, these 2 electrons would be removed. That means the electron configuration for $Sn^{2+}$ is $$Sn^{2+}: [Kr]4d^{10}5s^2$$ The above configuration is not a noble-gas configuration, so $Sn^{2+}$ does not have noble-gas configuration.
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