Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Additional Exercises - Page 721: 16.109c

Answer

The pH value is approximately $8.77$.

Work Step by Step

1. As we calculate in 109a, the pKb of that base is 9.16, use it to find the Kb: $Kb = 10^{-pKb}$ $Kb = 10^{-9.16}$ $Kb = 6.92 \times 10^{-10}$ 2. Now, find $[OH^-]$ $Kb = \frac{[OH^-][B^+]}{[BOH]}$ $[OH^-] = [B^+] = x$ $6.92 \times 10^{-10} = \frac{x^2}{0.05-x}$ Since $x$ has a very low value: $(0.05-x) \approx (0.05)$ $6.92 \times 10^{-10} = \frac{x^2}{0.05}$ $3.46 \times 10^{-11} = x^2$ $x = 5.88 \times 10^{-6}M = [OH^-]$ 3. Find the pH: $pOH = -log(5.88 \times 10^{-6})$ $pOH = 5.23$ $pH = 14 - pOH $ $pH = 8.77$
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