Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 14 - Chemical Kinetics - Exercises - Page 619: 14.24a

Answer

$rate=-\frac{1}{2}\frac{\Delta[H_{2}O]}{\Delta t}=\frac{1}{2}\frac{[H_{2}]}{\Delta t}=\frac{\Delta[O_{2}]}{\Delta t}$

Work Step by Step

Consider the chemical equation: aA + bB -> cC + dD The rate expression would be: $rate=-\frac{1}{a}\frac{\Delta[A]}{\Delta t}=-\frac{1}{b}\frac{[B]}{\Delta t}=\frac{1}{c}\frac{\Delta[C]}{\Delta t}=\frac{1}{d}\frac{\Delta[D]}{\Delta t}$ There are negative signs before A and B because their change in concentration ($\Delta [X]$) would be negative as their amount decreases over time. Therefore, the rate for this reaction should be: $rate=-\frac{1}{2}\frac{\Delta[H_{2}O]}{\Delta t}=\frac{1}{2}\frac{[H_{2}]}{\Delta t}=\frac{\Delta[O_{2}]}{\Delta t}$
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