Chemistry: Molecular Approach (4th Edition)

Published by Pearson
ISBN 10: 0134112830
ISBN 13: 978-0-13411-283-1

Chapter 16 - Exercises - Page 773: 95

Answer

a. Does not act as a weak base. b. Acts as a weak base: $$ClO^-(aq) + H_2O(l) \leftrightharpoons HClO(aq) + OH^- (aq)$$ c. Acts as a weak base: $$CN^-(aq) + H_2O(l) \leftrightharpoons HCN(aq) + OH^- (aq)$$ d. Does not act as a weak base.

Work Step by Step

The anion will act as a weak base in solution if it is a conjugate base of a weak acid. If it is the conjugate base of a strong acid, it will not ionize. a. $Br^- \longrightarrow HBr$. Since HBr is a strong acid, $Br^-$ does not ionize. b. $ClO^- \longrightarrow HClO$. Since HClO is a weak acid, $ClO^-$ acts as a weak base. c. $CN^- \longrightarrow HCN$. Since HCN is a weak acid, $CN^-$ acts as a weak base. d. $Cl^- \longrightarrow HCl$. Since HCl is a strong acid, $Cl^-$ does not ionize. To rewrite the equation, just write the reaction where the anion receives a proton $H^+$ from a water molecule. The reactants are the anions and a water molecule, and the products are the conjugate acid and a hydroxide ion.
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