Chemistry: Molecular Approach (4th Edition)

Published by Pearson
ISBN 10: 0134112830
ISBN 13: 978-0-13411-283-1

Chapter 16 - Exercises - Page 773: 87

Answer

a. $$NH_3(aq) + H_2O(l) \leftrightharpoons N{H_4}^+(aq) + OH^-(aq)$$ $$K_b = \frac{[NH{_4}^{+}][OH^-]}{[NH_3]}$$ b. $$HC{O_3}^-(aq) + H_2O(l) \leftrightharpoons H_2CO_3(aq) + OH^-(aq)$$ $$K_b = \frac{[H_2CO_3][OH^-]}{[HC{O_3}^-]}$$ c. $$CH_3NH_2(aq) + H_2O(l) \leftrightharpoons CH_3N{H_3}^+(aq) + OH^-(aq)$$ $$K_b = \frac{[CH_3N{H_3}^+][OH^-]}{[CH_3NH_2]}$$

Work Step by Step

A weak base ionizes receiving one proton $(H^+)$ from a water molecule, producing its conjugate acid and a hydroxide ion. $$K_b = \frac{[Products]}{[Reactants]}$$ * Water does not appear in the Kb expression since it is a liquid.
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