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The MO model describes the behavior of electrons in molecules by forming molecular orbitals through the combination of atomic orbitals. The local electron model, such as the Valence Bond theory, focuses on the concept of overlapping atomic orbitals to form covalent bonds. The MO model provides a more complete picture of electron distribution and is useful for understanding the electronic structure of molecules, while the local electron model is simpler and useful for explaining certain bonding patterns.
