Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 3 - Challenge Problems - Page 150j: 155

Answer

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Work Step by Step

To draw the Lewis structure for the N,N-dimethylformamide molecule, we need to follow these steps: 1. Determine the total number of valence electrons: - Nitrogen (N) has 5 valence electrons - Oxygen (O) has 6 valence electrons - Carbon (C) has 4 valence electrons - Hydrogen (H) has 1 valence electron each - Total valence electrons = 5 + 6 + 4 + (3 × 1) = 16 2. Arrange the atoms in the skeletal structure: - The skeletal structure is given as: $\underset {\uparrow }{C}H-CH_{3}$ 3. Draw the Lewis structure: - Place the carbon atom at the center, with the oxygen atom and the two methyl groups (CH3) attached. - Distribute the remaining valence electrons to form single bonds and fill the octet of each atom. - The resulting Lewis structure is: ${H3C-C(=O)-N(CH3)2}$ 4. Resonance structures: The presence of a partial double bond character in the C-N bond can be supported by the following resonance structures: Resonance Structure 1: ${H3C-C(=O)-N(CH3)2}$ Resonance Structure 2: ${H3C-C(=O)^{-}-N^{+}(CH3)2}$ The resonance structures show the delocalization of electrons between the carbon, oxygen, and nitrogen atoms, which contributes to the partial double bond character of the C-N bond.
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