Chemistry: Atoms First (2nd Edition)

Published by Cengage Learning
ISBN 10: 1305079248
ISBN 13: 978-1-30507-924-3

Chapter 2 - Exercises - Page 99b: 42

Answer

\(4.78 \times 10^5 \mathrm{~J}\)

Work Step by Step

The energy of a single UV photon can be calculated using the equation: \[ E = \frac{{hc}}{{\lambda}} \] where: - \( E \) is the energy of the photon, - \( h \) is Planck's constant (\(6.62607015 \times 10^{-34} \mathrm{~J \cdot s}\)), - \( c \) is the speed of light (\(3.00 \times 10^8 \mathrm{~m/s}\)), - \( \lambda \) is the wavelength of the UV light in meters. Given that the wavelength of the UV light is \(25 \mathrm{~nm}\), we need to convert it to meters by multiplying by \(10^{-9}\): \[ \lambda = 25 \times 10^{-9} \mathrm{~m} = 2.5 \times 10^{-8} \mathrm{~m} \] Now, we can calculate the energy of a single UV photon: \[ E = \frac{{(6.62607015 \times 10^{-34} \mathrm{~J \cdot s}) \times (3.00 \times 10^8 \mathrm{~m/s})}}{{2.5 \times 10^{-8} \mathrm{~m}}} \] \[ E \approx 7.95 \times 10^{-19} \mathrm{~J} \] For 1 mole of UV photons (\(6.022 \times 10^{23}\) photons), the total energy can be calculated by multiplying the energy of a single photon by Avogadro's number: \[ \text{Total energy} = (7.95 \times 10^{-19} \mathrm{~J/photon}) \times (6.022 \times 10^{23} \mathrm{~photons}) \] \[ \text{Total energy} \approx 4.78 \times 10^5 \mathrm{~J} \] So, the energy of 1 mole of UV photons with a wavelength of \(25 \mathrm{~nm}\) is approximately \(4.78 \times 10^5 \mathrm{~J}\).
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