Chemistry and Chemical Reactivity (9th Edition)

Published by Cengage Learning
ISBN 10: 1133949649
ISBN 13: 978-1-13394-964-0

Chapter 25 Nuclear Chemistry - Study Questions - Page 1007c: 37

Answer

(a) 15.8 years (b) 0.88 or 88%

Work Step by Step

(a) $\frac{1}{8}=\frac{1}{2}\times\frac{1}{2}\times\frac{1}{2}$ The time required is three half-lives. That is, $t=3\times5.27\,y=15.8\,years$ (b) Half-life $t_{1/2}=5.27\,y$ Decay constant $\lambda=\frac{0.693}{t_{1/2}}=\frac{0.693}{5.27\,y}=0.1315\,y^{-1}$ $t=1.0\,y$ Recall that $\ln(\frac{A}{A_{0}})=-\lambda t$ where $A_{0}$ is the activity of sample at the beginning and $A$ is the activity after time $t$. $\implies \ln(\frac{A}{A_{0}})=-(0.1315\,y^{-1})(1.0\,y)=-0.1315$ Taking the inverse $\ln$ of both the sides, we have $\frac{A}{A_{0}}=e^{-0.1315}=0.88$
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