Chemistry and Chemical Reactivity (9th Edition)

Published by Cengage Learning
ISBN 10: 1133949649
ISBN 13: 978-1-13394-964-0

Chapter 25 Nuclear Chemistry - Study Questions - Page 1007c: 35

Answer

(a) $\,^{222}_{86}Rn\rightarrow \,^{218}_{84}Po+\,^{4}_{2}\alpha$ (b) 8.87 days

Work Step by Step

(a) Alpha particle has mass=4 and charge=2. When $\alpha$ particle is emitted, mass of the nuclide is decreased by 4 and charge by 2. So Rn-222 decays to the nuclide with mass number=(222-4)=218 and atomic number=(86-2)=84. The nuclide formed is $\,^{218}_{84}Po$. The balanced nuclear equation is $\,^{222}_{86}Rn\rightarrow \,^{218}_{84}Po+\,^{4}_{2}\alpha$ (b) Recall that $\ln(\frac{A_{0}}{A})=kt=\frac{0.693}{t_{1/2}}\times t$ where $A_{0}$ is the initial activity and $A$ is the activity after time $t$. $\implies \ln(\frac{100}{20})=1.60944=\frac{0.693}{3.82\,d}\times(t)$ Or $t=\frac{1.60944\times3.82\,d}{0.693}=8.87\,d$
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