Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 13 - Sections 13.1-13.7 - Exercises - Problems by Topic - Page 638: 31a

Answer

i) $8.7\times10^{-3}$ M/s ii) $6.0\times10^{-3}$ M/s

Work Step by Step

Average rate of the reaction, $r_{av}$= $-\frac{\Delta [R]}{\Delta t}$ where $\Delta [R]$ is the change in concentration of the reactant and$\Delta t$ is the time taken for the change. i) Here, $\Delta [R]$= 0.913 M- 1.000 M = -0.087 M. $\Delta t$ = 10 s- 0 s = 10 s So $r_{av}=- (\frac{-0.087 M}{10 s}$)= $8.7\times10^{-3}$ M/s ii) In this case, $\Delta [R]$= 0.637M- 0.697 M = -0.060 M and $\Delta t$ = (50-40)s= 10s This gives $r_{av}= -(\frac{-0.060 M}{10 s})$= $6.0\times10^{-3}$ M/s
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