Answer
$54.9 \text{ L}$
Work Step by Step
$\Delta E = q+w$
$-102.5=52.5+w$
$w=-155$
$-P\Delta V=\frac{-155}{101.3}$
$-0.500(58.0-V_1)=-1.53$
$V_1=54.9 \text{ L}$
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