Chemistry (7th Edition)

Published by Pearson
ISBN 10: 0321943171
ISBN 13: 978-0-32194-317-0

Chapter 9 - Thermochemistry: Chemical Energy - Section Problems - Page 353: 103

Answer

$-108.7\,kJ$

Work Step by Step

We find: $\Delta H^{\circ}=\Sigma n_{p}\Delta H_{f}^{\circ}(products)-\Sigma n_{r}\Delta H_{f}^{\circ}(reactants)$ $=[4\,mol\times\Delta H_{f}^{\circ}(HNO_{3},aq)+2\,mol\times\Delta H_{f}^{\circ}(NO,g)]-[3\,mol\times\Delta H_{f}^{\circ}(N_{2}O_{4},g)+2\Delta H_{f}^{\circ}(H_{2}O,l)]$ $=[4\,mol(-207.4\,kJ/mol)+2\,mol(91.3\,kJ/mol)]-[3\,mol(11.1\,kJ/mol)+2(-285.8\,kJ/mol)]$ $=-108.7\,kJ$
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