Chemistry (7th Edition)

Published by Pearson
ISBN 10: 0321943171
ISBN 13: 978-0-32194-317-0

Chapter 16 - Applications of Aqueous Equilibria - Section Problems - Page 711: 102

Answer

$ K_{sp} (Ag_2C{O_3}) = (8.39 \times 10^{-12})$

Work Step by Step

1. Write the $K_{sp}$ expression: $ Ag_2CO_3(s) \lt -- \gt 2Ag^{+}(aq) + 1{CO_3}^{2-}(aq)$ $ K_{sp} = [Ag^{+}]^ 2[{CO_3}^{2-}]^ 1$ 2. Determine the ion concentrations: ** Considering "x", the molar solubility: $[Ag^{+}] = 2.56 \times 10^{-4}$ $= [Ag_2CO_3] * 2$ $[Ag_2C{O_3}^-] = \frac{2.56 \times 10^{-4}}{2} = 1.28 \times 10^{-4}$ $[{CO_3}^{2-}] = [Ag_2CO_3] * 1 = 1.28 \times 10^{-4}$ 3. Calculate the $K_{sp}$: $ K_{sp} = (2.56 \times 10^{-4})^ 2 \times (1.28 \times 10^{-4})^ 1$ $ K_{sp} = (6.554 \times 10^{-8}) \times (1.28 \times 10^{-4})$ $ K_{sp} = (8.388 \times 10^{-12})$
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