Chemistry (7th Edition)

Published by Pearson
ISBN 10: 0321943171
ISBN 13: 978-0-32194-317-0

Chapter 14 - Chemical Equilibrium - Worked Example - Page 560: 4

Answer

(a) $K_c = 1.38 \times 10^{-4}$ (b) $[C_3H_6O_3] = 0.992 M$

Work Step by Step

** Remember to put the balanced coefficients as the exponents of the concentrations. (a) $K_c = \frac{[Products]}{[Reactants]} = \frac{[H^+][C_3H_5O_3^-]}{[C_3H_6O_3]} = \frac{(3.65 \times 10^{-3})(3.65 \times 10^{-3})}{(9.64 \times 10^{-2})} = 1.38 \times 10^{-4}$ (b) Now that we know the equilibrium constant, substitute the values of the given concentrations, and solve for $[C_3H_6O_3]$: $1.38 \times 10^{-4} = \frac{[H^+][C_3H_5O_3^-]}{[C_3H_6O_3]} = \frac{(1.17 \times 10^{-2})(1.17 \times 10^{-2})}{[C_3H_6O_3]}$ $[C_3H_6O_3] = \frac{(1.17 \times 10^{-2})(1.17 \times 10^{-2})}{1.38 \times 10^{-4}} = 0.992$
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