Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 20 - Questions and Problems - Page 950: 20.28

Answer

64 hours.

Work Step by Step

Difference in time between 1.00 P.M. December 3, 2006 and 2:15 P.M. December 17, 2006 is 14 days, 1 hour and 15 minutes. In minutes, $t= (14\times24\times60)+(1\times60)+ 15=20235\,min$ Original activity $A_{0}=9.8\times10^{5}\,dpm$ Current activity $A=2.6\times10^{4}\,dpm$ $\ln(\frac{A_{0}}{A})=kt$ where $k$ is the decay constant. $\implies \ln(\frac{9.8\times10^{5}}{2.6\times10^{4}})=3.63=k(20235\,min)$ $\implies k=\frac{3.63}{20235\,min}=1.794\times10^{-4}\,min^{-1}$ Half-life $t_{1/2}=\frac{0.693}{k}=\frac{0.693}{1.794\times10^{-4}\,min^{-1}}$ $=3863\,min=\frac{3863}{60}\,h= 64\,h$
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