Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 17 - Questions and Problems - Page 827: 17.67

Answer

$Ag_2SO_4$, $Zn(OH)$, $Ba_2C_2O_4$ and $Ca_3(PO_4)_2$ are going to be more acidic in acidic solution than in pure water. Correct answer: (b), (c), (d) and (e).

Work Step by Step

(a) $I^-$ is the conjugate base of a strong acid (HI); therefore, it is not an electrolyte. (b), (d) and (e): $SO_4^{2-}$, $C_2O_4^{2-}$ and $PO_4^{3-}$: These 3 anions are the conjugate bases of weak acids, $HSO_4^-$, $HC_2O_4^-$ and $HPO_4^{2-}$, respectvely. Therefore, when a compound that contains one of them is added to an acidic solution, they will react with the hydronium ions. According to Le Chatelier's principle, if the concentration of the anions decrease (because it is reacting), the equilibrium will favor the dissolution. (c) The hydroxide ions will react with the hydronium ions from the acidic solution. According to Le Chatelier's principle, if the concentration of the anions decrease (because it is reacting), the equilibrium will favor the dissolution.
Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.